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\(nCaCl_2=\dfrac{2,22}{111}=0,02\left(mol\right)\)
\(nAgNO_3=\dfrac{1,7}{170}=0,01\left(mol\right)\)
\(CaCl_2+2AgNO_3\rightarrow2AgCl+Ca\left(NO_3\right)_2\)
1 2 2 1 (mol)
0,005 0,01 0,01 0,005
LTL : \(\dfrac{0,02}{1}>\dfrac{0,01}{2}\)
=> CaCl2 dư , AgNO3 đủ
\(m_{kt}=mAgCl=0,01.143,5=1,435\left(g\right)\)
c1:
\(m_{\left(muối\right)}=m_{Ca\left(NO_3\right)_2}=0,005.164=0,82\left(g\right)\)
c2:
BTKL:
\(mCaCl_{2\left(đủvspứ\right)}=0,005.111=0,555\left(g\right)\)
\(mCaCl_2+mAgNO_3=mAgCl+mCa\left(NO_3\right)_2\)
0,555 + 1,7 = 1,435 + \(mCa\left(NO_3\right)_2\)
\(\Rightarrow mCa\left(NO_3\right)_2=0,555+1,7-1,435=0,82\left(g\right)\)
\(n_{CuSO_4}=\dfrac{48}{160}=0,3mol\)
\(n_{BaCl_2}=\dfrac{82,2}{208}=0,39mol\)
\(CuSO_4+BaCl_2\rightarrow BaSO_4+CuCl_2\)
0,3 < 0,39 ( mol )
0,3 0,3 0,3 0,3 ( mol )
\(m_{BaCl_2\left(dư\right)}=\left(0,39-0,3\right).208=18,72g\)
\(m_{BaSO_4}=0,3.233=69,9g\)
Cách 1. \(m_{CuCl_2}=0,3.135=40,5g\)
Cách 2. \(m_{BaCl_2\left(pứ\right)}=0,3.208=62,4g\)
Áp dụng ĐL BTKL, ta có:
\(m_{CuSO_4}+m_{BaCl_2}=m_{BaSO_4}+m_{CuCl_2}\)
\(\rightarrow m_{CuCl_2}=48+62,4-69,9=40,5g\)
\(a,n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\left(1\right)\\ Theo.pt\left(1\right):n_{ZnCl_2}=n_{H_2}=0,2\left(mol\right)\\ b,m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\ c,PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\left(2\right)\\ THeo.pt\left(2\right):n_{Cu}=n_{H_2}=0,2\left(mol\right)\\ m_{Cu}=0,2.64=12,8\left(g\right)\)
\(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)
0,07 0,14 0,07 0,07
\(nCO_2=\dfrac{1,568}{22,4}=0,07\left(mol\right)\)
\(nNaOH=\dfrac{6,4}{23+17}=0,16\left(mol\right)\)
LTL : \(\dfrac{0,07}{1}< \dfrac{0,16}{2}\)
=> NaOH dư , CO2 đủ
\(nNaOH_{\left(dư\right)}=0,16-0,14=0,02\left(mol\right)\)
\(mNaOH_{\left(dư\right)}=0,02.40=0,8\left(g\right)\)
\(n_{H_2}=\dfrac{3,7185}{24,79}=0,15\left(mol\right)\)
PTHH: 2Al + 6HCl ---> 2AlCl3 + 3H2
0,1<---------------0,1<-----0,15
\(\Rightarrow\left\{{}\begin{matrix}a,m_{Al}=0,1.27=2,7\left(g\right)\\b,m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\end{matrix}\right.\)
nCuSO4=0,5.0,4=0,2 mol
CuSO4 +2NaOH=> Cu(OH)2+Na2SO4
0,2 mol =>0,2 mol
Cu(OH)2=> CuO+H2O
0,2 mol =>0,2 mol
kết tủa A là Cu(OH)2 m=98.0,2=19,6g
cr B là CuO m=0,2.80=16g
a. PTHH:
\(Ca+2H_2O--->Ca\left(OH\right)_2+H_2\left(1\right)\)
\(CaO+H_2O--->Ca\left(OH\right)_2\left(2\right)\)
b. Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT(1): \(n_{Ca}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{Ca}=0,1.40=4\left(g\right)\)
\(\Rightarrow\%_{m_{Ca}}=\dfrac{4}{9,6}.100\%=41,7\%\)
\(\%_{m_{CaO}}=100\%-41,7\%=58,3\%\)
c. Ta có: \(n_{CaO}=\dfrac{9,6-4}{56}=0,1\left(mol\right)\)
Ta có: \(n_{hh}=0,1+0,1=0,2\left(mol\right)\)
Theo PT(1,2): \(n_{Ca\left(OH\right)_2}=n_{hh}=0,2\left(mol\right)\)
\(\Rightarrow m_{Ca\left(OH\right)_2}=0,2.74=14,8\left(g\right)\)
\(n_{FeSO_4}=\dfrac{15,2}{152}=0,1mol\)
\(n_{NaOH}=\dfrac{40}{40}=1mol\)
\(FeSO_4+2NaOH\rightarrow Fe\left(OH\right)_2+Na_2SO_4\)
0,1 < 1 ( mol )
0,1 0,2 0,1 0,1 ( mol )
\(m_{Fe\left(OH\right)_2}=0,1.90=9g\)
\(m_{NaOH\left(dư\right)}=\left(1-0,2\right).40=32g\)
Cách 1.
\(m_{Na_2SO_4}=0,1.142=14,2g\)
Cách 2.
\(m_{NaOH\left(pứ\right)}=0,2.40=8g\)
Áp dụng ĐL BTKL, ta có:
\(m_{FeSO_4}+m_{NaOH}=m_{Fe\left(OH\right)_2}+m_{Na_2SO_4}\)
\(\rightarrow m_{Na_2SO_4}=15,2+8-9=14,2g\)