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a) \(n_{CH_4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
=> \(\%V_{CH_4}=\dfrac{3,36}{11,2}.100\%=30\%\)
=> \(\%V_{C_2H_4}=100\%-30\%=70\%\)
b) \(n_{C_2H_4}=\dfrac{11,2.70\%}{22,4}=0,35\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,15-->0,3
C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,35-->1,05
=> nO2 = 0,3 + 1,05 = 1,35 (mol)
=> VO2 = 1,35.22,4 = 30,24 (l)
a)
\(n_{Br_2}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,05<-0,05
=> \(n_{CH_4}=\dfrac{3,36}{22,4}-0,05=0,1\left(mol\right)\)
\(\%m_{CH_4}=\dfrac{0,1.16}{0,1.16+0,05.28}.100\%=53,33\%\)
\(\%m_{C_2H_4}=\dfrac{0,05.28}{0,1.16+0,05.28}.100\%=46,67\%\)
b)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,1-->0,2
C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,05--->0,15
=> \(V_{O_2}=\left(0,2+0,15\right).22,4=7,84\left(l\right)\)
\(n_{Br_2}=\dfrac{8}{160}=0,05mol\)
\(n_{hh}=\dfrac{5,6}{22,4}=0,25mol\)
\(C_2H_4+Br_2\rightarrow C_2H_2Br_4\)
0,05 0,05 ( mol )
\(\%V_{C_2H_4}=\dfrac{0,05}{0,25}.100=20\%\)
\(\%V_{CH_4}=100\%-20\%=80\%\)
\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)
0,2 0,4 ( mol )
\(C_2H_4+5O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)
0,05 0,25 ( mol )
\(V_{kk}=V_{O_2}.5=\left(0,4+0,25\right).22,4.5=14,56.5=72,8l\)
\(n_{hh}=\dfrac{3,36}{22,4}=0,15mol\)
\(n_{Br_2}=\dfrac{2,4}{160}=0,015mol\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
0,0075 0,015 ( mol )
\(V_{C_2H_2}=0,0075.22,4=0,168l\)
\(V_{CH_4}=3,36-0,168=3,192l\)
\(\%V_{C_2H_2}=\dfrac{0,168}{3,36}.100=5\%\)
\(\%V_{CH_4}=100\%-5\%=95\%\)
Cho hỗn hợp qua dung dịch brom chỉ có etylen tác dụng.
\(n_{Br_2}=0,25\cdot1,5=0,375mol\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,375 0,375
\(V_{C_2H_4}=0,375\cdot22,4=8,4l\Rightarrow V_{CH_4}=11-8,4=2,6l\)
a, PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)
Giả sử: \(\left\{{}\begin{matrix}n_{C_2H_4}=x\left(mol\right)\\n_{C_2H_2}=y\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow x+y=\dfrac{1,344}{22,4}=0,06\left(1\right)\)
Ta có: \(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)
Theo PT: \(n_{Br_2}=n_{C_2H_4}+2n_{C_2H_2}=x+2y\left(mol\right)\)
⇒ x + 2y = 0,1 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,02\left(mol\right)\\y=0,04\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,02}{0,06}.100\%\approx33,33\%\\\%\text{ }V_{C_2H_2}\approx66,67\%\end{matrix}\right.\)
b, Ta có: 1/2 hỗn hợp khí gồm: 0,01 mol C2H4 và 0,02 mol C2H2.
PT: \(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)
Theo PT: \(n_{CO_2}=2n_{C_2H_4}+2n_{C_2H_2}=0,06\left(mol\right)\)
\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
Theo PT: \(n_{CaCO_3}=n_{CO_2}=0,06\left(mol\right)\)
\(\Rightarrow m_{cr}=m_{CaCO_3}=0,06.100=6\left(g\right)\)
Bạn tham khảo nhé!
a, \(n_{hh}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
\(n_{Br2}=\dfrac{24}{160}=0,15\left(mol\right)\)
\(CH_2=CH_2+Br_2\rightarrow CH_2+CH_2\)
/Br /Br
0,15mol<----- 0,15mol
\(nC_2H_4=0,15\left(mol\right)\)
\(\Rightarrow nCH_3=0,35-0,15=0,2\left(mol\right)\)
\(\%VCH_4=\%nCH_4=\dfrac{0,2}{0,35}.100\%=57,14\%\)
\(\%VC_2H_4=100-57,14=42,86\%\)
\(C_2H_2+2Br_2->C_2H_2Br_4\\ n_{hh}=\dfrac{3,36}{22,4}=0,15mol\\ n_{CH_4}=\dfrac{2,24}{22,4}=0,1mol\\ n_{C_2H_2}=0,05mol\\ n_{Br_2}=2.0,05=0,1mol\\ m_{Br_2}=0,1.160=16g\\ \%V_{CH_4}=\dfrac{0,1}{0,15}.100\%=66,67\%\\ \%V_{C_2H_2}=33,33\%\)
