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Bài 8:
\(n_{H_2}=\dfrac{7,437}{24,79}=0,3\left(mol\right)\)
PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
_____0,2______0,6_____0,2____0,3 (mol)
a, \(m_{Al}=0,2.27=5,4\left(g\right)\)
b, \(C_{M_{HCl}}=\dfrac{0,6}{0,3}=2\left(M\right)\)
c, \(C_{M_{AlCl_3}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
Bài 9:
Ta có: \(n_{H_2}=\dfrac{2,479}{24,79}=0,1\left(mol\right)\)
PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\)
a, \(n_{Mg}=n_{H_2}=0,1\left(mol\right)\Rightarrow m_{Mg}=0,1.24=2,4\left(g\right)\)
\(\Rightarrow m_{MgO}=8,4-2,4=6\left(g\right)\)
b, \(n_{MgO}=\dfrac{6}{40}=0,15\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Mg}+2n_{MgO}=0,5\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,5.36,5}{3,65\%}==500\left(g\right)\)
Bài 6:
\(n_{Fe\left(OH\right)_3}=\dfrac{21,4}{107}=0,2\left(mol\right)\)
PT: \(Fe\left(OH\right)_3+3HCl\rightarrow FeCl_3+3H_2O\)
_______0,2________0,6______0,2 (mol)
a, \(C\%_{HCl}=\dfrac{0,6.36,5}{200}.100\%=10,95\%\)
b, \(C\%_{FeCl_3}=\dfrac{0,2.162,5}{21,4+200}.100\%\approx14,68\%\)
Bài 7:
\(m_{H_2SO_4}=100.9,8\%=9,8\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{9,8}{98}=0,1\left(mol\right)\)
PT: \(ZnO+H_2SO_4\rightarrow ZnSO_4+H_2O\)
______0,1______0,1_______0,1 (mol)
a, \(m_{ZnO}=0,1.81=8,1\left(g\right)\)
b, \(C\%_{ZnSO_4}=\dfrac{0,1.161}{8,1+100}.100\%\approx14,89\%\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
a, \(n_{H_2}=n_{Mg}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.24,79=4,958\left(l\right)\)
b, \(n_{HCl}=2n_{Mg}=0,4\left(mol\right)\Rightarrow m_{ddHCl}=\dfrac{0,4.36,5}{20\%}==73\left(g\right)\)
c, \(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
Theo PT: \(n_{Ba\left(OH\right)_2}=\dfrac{1}{2}n_{HCl}=0,2\left(mol\right)\)
\(\Rightarrow V_{Ba\left(OH\right)_2}=\dfrac{0,2}{2,5}=0,08\left(l\right)\)
a, \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: R + 2HCl → RCl2 + H2
Mol: 0,15 0,3 0,15
\(M_R=\dfrac{8,4}{0,15}=56\left(g/mol\right)\)
⇒ R là sắt (Fe)
b, \(m_{ddHCl}=\dfrac{0,3.36,5.100}{15}=73\left(g\right)\)
\(n_{HCl}=0.1\cdot1=0.1\left(mol\right)\)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\)
\(0.05...........0.1\)
\(m_{MgO}=0.05\cdot24=1.2\left(g\right)\)
\(MgO+2HCl \to MgCl_2+H_2O\\ n_{HCl}=0,1(mol)\\ n_{MgO}=0,05(mol)\\ m_{MgO}=0,05.40=2(g)\\ \to A\)
Bài 14:
Ta có: \(n_{BaCO_3}=\dfrac{39,4}{197}=0,2\left(mol\right)\)
PT: \(BaCO_3+2HCl\rightarrow BaCl_2+CO_2+H_2O\)
a, \(n_{CO_2}=n_{BaCO_3}=0,2\left(mol\right)\Rightarrow V_{CO_2}=0,2.24,79=4,958\left(l\right)\)
b, Sửa đề: tính khối lượng dung dịch HCl → tính nồng độ % dd HCl.
\(n_{HCl}=2n_{BaCO_3}=0,4\left(mol\right)\Rightarrow m_{ddHCl}=\dfrac{0,4.36,5}{100}.100\%=14,6\%\)
c, \(n_{BaCl_2}=n_{BaCO_3}=0,2\left(mol\right)\)
Ta có: m dd sau pư = 39,4 + 100 - 0,2.44 = 130,6 (g)
\(\Rightarrow C\%_{BaCl_2}=\dfrac{0,2.208}{130,6}.100\%\approx31,85\%\)
Bài 12:
Ta có: \(n_{MgCO_3}=\dfrac{25,2}{84}=0,3\left(mol\right)\)
PT: \(MgCO_3+2HCl\rightarrow MgCl_2+CO_2+H_2O\)
a, Theo PT: \(n_{CO_2}=n_{MgCO_3}=0,3\left(mol\right)\)
\(\Rightarrow V_{CO_2}=0,3.24,79=7,437\left(l\right)\)
b, Ta có: m dd sau pư = 25,2 + 200 - 0,3.44 = 212 (g)
Theo PT: \(n_{MgCl_2}=n_{MgCO_3}=0,3\left(mol\right)\)
\(\Rightarrow C\%_{MgCl_2}=\dfrac{0,3.95}{212}.100\%\approx13,44\%\)
Bài 13:
Ta có: \(n_{CaCO_3}=\dfrac{10}{100}=0,1\left(mol\right)\)
PT: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
1. \(n_{CO_2}=n_{CaCO_3}=0,1\left(mol\right)\) \(\Rightarrow V_{CO_2}=0,1.24,79=2,479\left(l\right)\)
2. \(n_{HCl}=2n_{CaCO_3}=0,2\left(mol\right)\Rightarrow m_{ddHCl}=\dfrac{0,2.36,5}{7,3\%}=100\left(g\right)\)
3. Ta có: m dd sau pư = 10 + 100 - 0,1.44 = 105,6 (g)
Theo PT: \(n_{CaCl_2}=n_{CaCO_3}=0,1\left(mol\right)\)
\(\Rightarrow C\%_{CaCl_2}=\dfrac{0,1.111}{105,6}.100\%\approx10,51\%\)
a, \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
Chất X là MgCl2, Y là khí H2
PTHH: Mg + 2HCl → MgCl2 + H2
Mol: 0,2 0,4 0,2 0,2
b, \(V=\dfrac{0,4}{2}=0,2\left(l\right)=200\left(ml\right)\)
\(V_1=0,2.22,4=4,48\left(l\right)\)
c, \(C_{M_{ddMgCl_2}}=\dfrac{0,2}{0,2}=1M\)
d,
PTHH: M2Ox + 2xHCl → 2MClx + xH2O
Mol: \(\dfrac{0,2}{x}\) 0,4
\(\Rightarrow M_{M_2O_x}=\dfrac{16,2}{\dfrac{0,2}{x}}=81x\left(g/mol\right)\)
Vì M là kim loại nên có hóa trị l,ll,lll
⇒ M là kẽm (Zn)